Question does the new Voice/audio capture feature capture the voices of players on PC or PS5?

you could use a capture card on a pc and connect the 360 there and have the voice output to the speakers,

Than use the software that captures the video to capture the audio also

The xbox DVR does not capture voice chat. It only captures Gameplay

Hi there,

Thanks for your post! Natively, the GameDVR function only captures video and audio from the game being recorded. In order to get voice audio for your gameplay, you may want to consider an external audio capture device or a capture card that supports capturing
audio of these together.

I hope this information helps.

I'll work on it - I'm new to game capturing but I do possess the required skills to do simple voice over audio

It will only record in-game chat if you set sound output to BOTH the connected headset and TV speakers (Xbox Guide>Preferences>Voice) and are using an audio connection that also passes through the Avermedia capture device. For example, HDMI from the Xbox
360 to your capture device will capture voice with it set to BOTH since HDMI carries audio and video. Red and White RCA cables to the capture device will also capture ingame chat.

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So basically, if you do not want this, only choose output to Headset. Not TV speakers or Both.