Can I unlink my Microsoft account from Minecraft on PlayStation

I need to unlink my PlayStation Network account from my old Microsoft account which I don’t remember, & link it to a new Microsoft account to play Minecraft

You can unlink the psn account however you CANT link a different one.

Note: Once a Microsoft account has been linked to a PlayStation® account, neither the Microsoft account nor the PlayStation™ Network account can be associated with a different account. 

If you choose to unlink accounts, then purchases will be returned to the account which made the purchase. Even after unlinking, Microsoft and PlayStation® accounts can only be re-linked to the original account.

This is coming right from the Minecraft website

https://help.minecraft.net/hc/en-us/articles/360037725571-Minecraft-for-PlayStation-TM-4-FAQ

That's really weird, since when you unlink a Minecraft/Microsoft account from a Playstation ID it can only be linked to the same Playstation ID.

Are you completely sure you are signed in with the correct Playstation ID and trying to login with the correct Minecraft/Microsoft Account?

I don’t know what email I used to link to my PS5 for Minecraft account. Could somebody unlink the account connected to my minecraft account if not can you tell me what email is linked to my minecraft account. Would I have to go to PlayStation to get it unlinked or do I go to Microsoft since it’s the accounts that are needed.

Even if you could unlink the account you wouldnt be able to link a different one.

Per https://help.minecraft.net/hc/en-us/articles/360037725571-Minecraft-for-PlayStation-FAQ

Note: Once a Microsoft account has been linked to a PlayStation® account, neither the Microsoft account nor the PlayStation™ Network account can be associated with a different account. 

If you choose to unlink accounts, then purchases will be returned to the account which made the purchase. Even after unlinking, Microsoft and PlayStation® accounts can only be re-linked to the original account.

This is a Sony imposed restriction, not Microsoft/Xbox.

Hello,

Please check out this page: Minecraft for PlayStation® FAQ – Home

It states:

Linking a Microsoft account to a Playstation® account

WARNING Once a Microsoft account has been linked to a PlayStation® account, neither the Microsoft account nor the PlayStation™ Network account can be associated with a different account. 

If you choose to unlink accounts, then purchases will be returned to the account which made the purchase. Even after unlinking, Microsoft and PlayStation® accounts can only be re-linked to the original account.

What happens when I unlink my Microsoft account?

IMPORTANT Once a Microsoft account has been linked to a PlayStation™ Network account, it cannot be unlinked without loss of access to entitlements and Minecoins on other platforms. 

According to this thread you can unlink the accounts: Minecraft PS4: Unlinking Microsoft Account - Microsoft Community

However, even if you unlink it, according to Mojang you can only Re-link it to the original account, you cannot link a different PlayStation account to the Microsoft account.

Thank you,

Hi Ryan, my name is Rodrigo. I'm an Independent Advisor and a member of the Microsoft community and I'd love to assist you today.

I am sorry to hear that.

You can only link one PSN account to one Minecraft account, you won't be able to link another Microsoft account to your PSN account.

I took this from the Minecraft site:

"WARNING: Once a Microsoft account has been linked to a PlayStation account, neither the Microsoft account nor the PlayStation Network account can be associated with a different account.

If you choose to unlink accounts, then purchases will be returned to the account that made the purchase. Even after unlinking, Microsoft and PlayStation accounts can only be re-linked to the original account."

For more information, you can use this link: help.minecraft.net/hc/articles/360037725571-Minecraft-for-PlayStation-FAQ#h_01FANTJ5HE05XVRKTBP5BN1WCT