Problem with Xbox Game Bar and Windows Capture Settings shortcuts keys overlapping

Yes, the default key shortcut is Win Key+Alt+PrntScrn. You can open the Game Bar app and click on the gear icon and check your hot key settings to be sure what captures are set to.

Hello EthanSL
My name is Ezequiel. I'm an Independent Consultant and I'm happy to help you today. Yes is possible.

While you're playing a game, press the Windows logo key + G to open Xbox Game Bar.
Choose Widget Menu > Capture.
Choose Start recording, Take screenshot, or Record last….
Record last… turns the most recent moments of play into a game clip when background recording is turned on. Set the duration in Windows Settings > Gaming > Captures.
Find your game clips and screenshots by opening Game Bar and selecting Widget Menu > Gallery.
To set your resolution and upmarket everything to 4K:
To capture game footage, make sure the Record in the background while I'm playing a game checkbox is selected in Game Bar settings (or turn it on in Windows Settings > Gaming > Captures).
For some PC games, Game Bar won't appear in full screen mode. To start and stop recordings without Game Bar, use the keyboard shortcut Windows logo key + Alt + R. The screen will flash to indicate the start and end of recording. If background recording is on, Windows logo key + Alt + G will record the last moments of play.
If the shortcuts don't work for a full-screen game, press the Windows logo key + G. The screen will flash twice to confirm that the game has been recognised. Then, re-open the game in full screen mode.

https://support.xbox.com/en-GB/help...cialize/record-game-clips-game-bar-windows-10

If you have any other questions, please contact me and I'll be here to help.

Hello Rocco how are you?

My name is Ezequiel I'm an Independent Consultant.

Make sure you have the latest updates on your Windows device.

Press the Start button and choose Settings.

Go to Update & Security (Windows Update on Windows 11) and select Check for Updates.

Check the Game Bar settings. Press the Start button and choose Settings.

Go to Games > Xbox Game Bar, then turn on Record Game Clips, Screenshots, and Stream Using Game Bar.

When playing games, press Windows logo key \uE560 + G to open the Game Bar.

Select Enable game features to have this app record gameplay when trying to use game features like streaming or capturing.

Your game may be running in full screen mode. See the section “How do I record a game if it is in full screen mode?” section above.

Make sure you update your graphics drivers. To see:
Hardware requirements for capturing on Windows
Try choosing a different display option for your game, such as borderless windows.

The game may be blocking custom keyboard shortcuts. See the section “Why don't my keyboard shortcuts for the Game Bar work?” section below.
A small number of PCs and accessories do not support the Windows logo key.

See your device manufacturer's website for more information.
If your keyboard doesn't have a built-in Windows logo key, create a custom keyboard shortcut to open Game Bar.

Press the Start button , select Settings > Gaming > Xbox Game bar and enter a new shortcut.

I'm sending you a link that has more other settings that I believe will solve your problem.

https://support.xbox.com/help/games-apps/game-setup-and-play/troubleshoot-game-bar-windows

Hi, and thanks for reaching out. My name is Miguel O., Sorry to hear you're experiencing this issue!

1. Make sure you have the latest updates on your Windows device. Press the Start button , then choose Settings. Go to Update & security (Windows Update on Windows 11), then select Check for updates.

2. Check your Game Bar settings. Press the Start button , then choose Settings. Go to Gaming > Xbox Game bar, then turn on Record game clips, screenshots, and broadcast using Game bar.

3. When playing a game, press the Windows logo key + G to open Game Bar. Select the Enable gaming features for this app to record gameplay when trying to use gaming features such as broadcasting or capturing.

4. Your game may be running in full-screen mode. See the “How do I record a game if it’s in full-screen mode?” section, above.

5. Make sure you’ve updated your graphics drivers.

6. Try choosing a different display option for your game, such as borderless windows.

7. The game might be blocking custom keyboard shortcuts. See the “Why don't my keyboard shortcuts for Game Bar work?” section, below.

8. A small number of PCs and accessories don’t support the Windows logo key. Check your device manufacturer’s website for more info.

9. If your keyboard doesn’t have the Windows logo key built in, create a custom keyboard shortcut to open Game Bar. Press the Start button , select Settings > Gaming > Xbox Game bar, and then enter a new shortcut.

Fix problems with Xbox Game Bar on
Windows 10. If nothing happens when you press the Windows logo key + G, check your
Xbox Game Bar settings. ... If Xbox Game Bar doesn't appear for a full-screen
game, try keyboard shortcuts: Press the Windows logo key + Alt + R to
start recording a clip, then press it again to stop.